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  4. Patterns and driving forces of dimensionality-dependent charge density waves in 2H-type transition metal dichalcogenides
 
research article

Patterns and driving forces of dimensionality-dependent charge density waves in 2H-type transition metal dichalcogenides

Lin, Dongjing
•
Li, Shichao
•
Wen, Jinsheng
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May 15, 2020
Nature Communications

Charge density wave (CDW) is a startling quantum phenomenon, distorting a metallic lattice into an insulating state with a periodically modulated charge distribution. Astonishingly, such modulations appear in various patterns even within the same family of materials. Moreover, this phenomenon features a puzzling diversity in its dimensional evolution. Here, we propose a general framework, unifying distinct trends of CDW ordering in an isoelectronic group of materials, 2H-MX2 (M = Nb, Ta and X = S, Se). We show that while NbSe2 exhibits a strongly enhanced CDW order in two dimensions, TaSe2 and TaS2 behave oppositely, with CDW being absent in NbS2 entirely. Such a disparity is demonstrated to arise from a competition of ionic charge transfer, electron-phonon coupling, and electron correlation. Despite its simplicity, our approach can, in principle, explain dimensional dependence of CDW in any material, thereby shedding new light on this intriguing quantum phenomenon and its underlying mechanisms. The dimensional dependence of charge density wave (CDW) in two-dimensional dichalcogenides remains puzzled. Here, Lin et al. study trends of CDW ordering in an isoelectronic group of materials 2H-MX2 and provide a unified understanding involving several microscopic factors.

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Type
research article
DOI
10.1038/s41467-020-15715-w
Web of Science ID

WOS:000536569900004

Author(s)
Lin, Dongjing
Li, Shichao
Wen, Jinsheng
Berger, Helmuth  
Forro, Laszlo  
Zhou, Huibin
Jia, Shuang
Taniguchi, Takashi
Watanabe, Kenji
Xi, Xiaoxiang
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Date Issued

2020-05-15

Publisher

Nature Research

Published in
Nature Communications
Volume

11

Issue

1

Article Number

2406

Subjects

Multidisciplinary Sciences

•

Science & Technology - Other Topics

•

ferromagnetism

•

discovery

•

order

Note

This article is licensed under a Creative Commons Attribution 4.0 International License

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPMC  
Available on Infoscience
June 14, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/169281
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