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  4. Quasi-harmonic computations of thermodynamic parameters of olivines at high-pressure and high-temperature. A comparison with experiment data
 
conference paper

Quasi-harmonic computations of thermodynamic parameters of olivines at high-pressure and high-temperature. A comparison with experiment data

Wang, Y.B.
•
Gillet, P.  
•
Ricard, Y.
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1996
Physics Of The Earth And Planetary Interiors
Session SW2 of the XXI IUGG General Assembly - Thermoelastic Properties of Deep Mantle Phases

Specific volumes of forsterite and San Carlos olivine have been measured by in-situ X-ray diffraction at simultaneously high pressure and high temperature up to 7 GPa and 1300 K in a cubic-anvil press coupled to synchrotron radiation. No difference could be evidenced between the thermal pressure of the two compounds. It has been shown that the parameter alpha K-T is volume-independent within the volume range investigated in this study for both forsterite and San Carlos olivine. A quasi-harmonic calculation of the high-pressure high-temperature specific volumes of forsterite has been performed and shown to be in good agreement with the experimental results. Then, a self consistent model of all the thermodynamic functions of forsterite was constructed, the input consisting of the experimental ultrasonic and vibrational spectroscopic data exclusively. The model accurately reproduces not only the experimental P-V-T data measured in this study, but also the high-temperature, 1 bar thermal expansion, the adiabatic incompressibility, the constant pressure specific heat and the entropy measurements, without using other a priori information.

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Type
conference paper
Web of Science ID

WOS:A1996VZ27700003

Author(s)
Wang, Y.B.
Gillet, P.  
Ricard, Y.
Guyot, F.
Date Issued

1996

Published in
Physics Of The Earth And Planetary Interiors
Volume

98

Start page

17

End page

29

Subjects

Lattice-Vibrations

•

Mantle Pressures

•

Forsterite

•

Equation

•

Minerals

•

State

•

Spectroscopy

•

Mg2Sio4

•

Heat

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
EPSL  
Event nameEvent placeEvent date
Session SW2 of the XXI IUGG General Assembly - Thermoelastic Properties of Deep Mantle Phases

BOULDER, CO

Jul 02-14, 1995

Available on Infoscience
September 29, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/71312
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