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  4. Photodissociation of Alkyl Iodides in Helium Nanodroplets III: Recombination
 
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research article

Photodissociation of Alkyl Iodides in Helium Nanodroplets III: Recombination

Braun, Andreas
•
Drabbels, Marcel  
2007
The Journal of Chemical Physics

The recombination of fragments resulting from the photodissociation of (fluorinated) alkyl iodides in helium nanodroplets at a wavelength of 266 nm has been investigated by means of ion imaging techniques. It is found that in the case of CH3I an appreciable fraction of the fragments recombine in the aftermath of the photolysis. The proposed mechanism involves a complete translational relaxation of both photofragments inside the nanodroplets followed by geminate recombination of the two fragments. In contrast to CH3I, no recombination is observed for CF3I. This is attributed to the larger masses and the different initial kinetic energies of the fragments produced by the photolysis of CF3I, which strongly diminishes the fragment thermalization efficiency.

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Type
research article
DOI
10.1063/1.2767263
Web of Science ID

WOS:000249667400020

Author(s)
Braun, Andreas
•
Drabbels, Marcel  
Date Issued

2007

Published in
The Journal of Chemical Physics
Volume

127

Article Number

114305

Subjects

helium droplets

•

dissociation

•

recombination

•

dynamics

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
April 26, 2007
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/6277
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