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research article

Rheological Properties of Hyperbranched Polymer/Poly(ethylene Terephthalate) Reactive Blends

Kil, S. B.
•
Augros, Y.
•
Leterrier, Y.  
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2003
Polymer Engineering and Science

The rheological properties in solution, in shear and in uniaxial elongation of poly(ethylene terephthalate) (PET) reacted together with hyperbranched polymers (HBPs) were investigated. Two different PET grades, of low and high molecular weights, were compounded with sub- to over-stoichiometric concentrations of HBPs of second and fourth pseudo-generation, and subsequently subjected to a solidstate polycondensation (SSP). The formation of microgels, which occurs at high HBP concentration, gave rise to a large increase in melt elasticity and a related decrease in melt strength. At low HBP concentrations, the complex viscosity of the unreacted HBP/PET was considerably reduced, thus demonstrating a lubrication effect of the HBP molecules. During SSP, the intrinsic and shear viscosities exhibited a gradual increase, which was similar for both PET and HBP/PET blends, and was correlated to an increase in molecular weight, through linear-chain extension and branching reactions. The elongational viscosity of the reactive blends was also increased as a function of reaction time, and this increase was much larger in the case of the HBP/PET blends. A 400% increase in melt strength of the PET was obtained by combining SSP and trace amounts of an HBP of second generation, without any decrease in drawability.

  • Details
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Type
research article
DOI
10.1002/pen.10028
Author(s)
Kil, S. B.
Augros, Y.
Leterrier, Y.  
Månson, J.-A. E.  
Date Issued

2003

Published in
Polymer Engineering and Science
Volume

43

Issue

2

Start page

329

End page

343

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LTC  
Available on Infoscience
June 26, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/232334
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