Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Chemical shrinkage of ye'elimite with and without gypsum addition
 
research article

Chemical shrinkage of ye'elimite with and without gypsum addition

Bullerjahn, Frank  
•
Skocek, Jan
•
Ben Haha, Mohsen
Show more
March 10, 2019
Construction And Building Materials

Ye'elimite (Ca4Al6O12SO4 or C(4)A(3)S) is the main hydraulic mineral present in calcium sulphoaluminate cement (CSA). Its reaction is responsible for the (early) hydration and associated cement properties such as the chemical shrinkage. This paper discusses the evolution of chemical shrinkage and related hydration reactions of stoichiometric ye'elimite in the absence and presence of gypsum. The measurements reveal a transitory chemical expansion followed by recovery to the original value for both binders. The shrinkage evolution is linked to the changes within the X-ray amorphous phases formed during hydration. This amorphous component is composed of several metastable hydrates such as aluminium hydroxide gel, which undergo subsequent recrystallization with time. This causes the release of some of the bound water and coincides with the period during which the chemical expansion occurs. (C) 2018 Elsevier Ltd. All rights reserved.

  • Details
  • Metrics
Type
research article
DOI
10.1016/j.conbuildmat.2018.12.170
Web of Science ID

WOS:000458942400069

Author(s)
Bullerjahn, Frank  
Skocek, Jan
Ben Haha, Mohsen
Scrivener, Karen  
Date Issued

2019-03-10

Publisher

ELSEVIER SCI LTD

Published in
Construction And Building Materials
Volume

200

Start page

770

End page

780

Subjects

Construction & Building Technology

•

Engineering, Civil

•

Materials Science, Multidisciplinary

•

Engineering

•

Materials Science

•

ye'elimite hydration

•

chemical expansion

•

amorphous aluminium hydroxide

•

bound water

•

monocalcium aluminate

•

thermal-analysis

•

early hydration

•

hydroxide

•

sulfate

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMC  
Available on Infoscience
June 18, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/157008
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés