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  4. Microwave plasma-assisted reactive HiPIMS of InN films: Plasma environment and material characterisation
 
research article

Microwave plasma-assisted reactive HiPIMS of InN films: Plasma environment and material characterisation

Hain, Caroline
•
Schweizer, Peter
•
Sturm, Patrick
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December 27, 2022
Surface & Coatings Technology

This work focuses on the low temperature fabrication process of InN thin films via microwave plasma-assisted reactive high power impulse magnetron sputtering (MAR-HiPIMS). The influence of microwave plasma on the HiPIMS discharge process at various nitrogen flows and microwave powers was monitored and characterised through in situ diagnostics, including following HiPIMS I(V,t) curves, optical emission spectroscopy (OES), as well as performing time-resolved Langmuir probe and time-of-flight mass spectroscopy (ToF-MS) measurements. This was followed by the deposition of InN films via standard reactive HiPIMS (reference sample) and MAR-HiPIMS and their characterisation via X-ray diffraction (XRD), reflectometry (XRR), as well as scanning and transmission electron microscopy (SEM, TEM). It was found that the microwave plasma facilitates the dissoci-ation/activation of nitrogen species and supplies seed electrons to the magnetron discharge plasma. Furthermore, the energy of the incoming ions was determined via ToF-MS, and it was possible to identify their plasma origin and temporal behaviour. The produced R-HiPIMS sample was highly metallic, with no nitride phase detected. The MAR-HiPMS film, however, was stoichiometric and exhibited (0002) direction texturing, with an optical bandgap of approx. 1.5 eV, electron concentration of 2.72 x 1020 cm -3 and electron mobility of 7.16 cm2V- 1s- 1 (in the range for polycrystalline InN).

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Type
research article
DOI
10.1016/j.surfcoat.2022.129188
Web of Science ID

WOS:000917356000001

Author(s)
Hain, Caroline
Schweizer, Peter
Sturm, Patrick
Borzi, Aurelio
Thomet, Jonathan E.
Michler, Johann
Hessler-Wyser, Aicha  
Nelis, Thomas
Date Issued

2022-12-27

Publisher

ELSEVIER SCIENCE SA

Published in
Surface & Coatings Technology
Volume

454

Article Number

129188

Subjects

Materials Science, Coatings & Films

•

Physics, Applied

•

Materials Science

•

Physics

•

microwave plasma

•

reactive hipims

•

indium7 nitride

•

plasma characterisation

•

tof-ms

•

indium nitride

•

band-gap

•

deposition

•

growth

•

absorption

•

mechanisms

•

emission

•

design

Editorial or Peer reviewed

REVIEWED

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February 13, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/194806
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