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research article

Survival of newly formed particles in haze conditions

Marten, Ruby
•
Xiao, Mao
•
Rorup, Birte
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May 1, 2022
Environmental Science-Atmospheres

Intense new particle formation events are regularly observed under highly polluted conditions, despite the high loss rates of nucleated clusters. Higher than expected cluster survival probability implies either ineffective scavenging by pre-existing particles or missing growth mechanisms. Here we present experiments performed in the CLOUD chamber at CERN showing particle formation from a mixture of anthropogenic vapours, under condensation sinks typical of haze conditions, up to 0.1 s(-1). We find that new particle formation rates substantially decrease at higher concentrations of pre-existing particles, demonstrating experimentally for the first time that molecular clusters are efficiently scavenged by larger sized particles. Additionally, we demonstrate that in the presence of supersaturated gas-phase nitric acid (HNO3) and ammonia (NH3), freshly nucleated particles can grow extremely rapidly, maintaining a high particle number concentration, even in the presence of a high condensation sink. Such high growth rates may explain the high survival probability of freshly formed particles under haze conditions. We identify under what typical urban conditions HNO3 and NH3 can be expected to contribute to particle survival during haze.

  • Details
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Type
research article
DOI
10.1039/d2ea00007e
Web of Science ID

WOS:000870720400013

Author(s)
Marten, Ruby
Xiao, Mao
Rorup, Birte
Wang, Mingyi
Kong, Weimeng
He, Xu-Cheng
Stolzenburg, Dominik
Pfeifer, Joschka
Marie, Guillaume
Wang, Dongyu S.
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Date Issued

2022-05-01

Publisher

ROYAL SOC CHEMISTRY

Published in
Environmental Science-Atmospheres
Volume

2

Issue

3

Start page

491

End page

499

Subjects

Environmental Sciences

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Meteorology & Atmospheric Sciences

•

Environmental Sciences & Ecology

•

Meteorology & Atmospheric Sciences

•

atmospheric particles

•

growth-rate

•

npf events

•

urban

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nucleation

•

acid

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

Available on Infoscience
November 7, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/192039
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