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research article
Versatile palladium-catalyzed double carbonylation of aryl bromides
A versatile palladium-catalyzed double carbonylation of aryl bromides has been developed. Using Pd(OAc)2/BuPAd2 as the catalyst system and DBU as the base, under relatively low CO pressure, various a-ketoamides were produced in good yields. In order to get insight into the reaction pathway, real time NMR studies were performed as well and a correlated reaction mechanism is been given.
Type
research article
Web of Science ID
WOS:000415661300009
Authors
Publication date
2017
Published in
Volume
53
Start page
12422
End page
12425
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
November 11, 2017
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