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  4. Transformation between diphosphinoamines and iminobiphosphines: a reversible p-n-p <-> N=P-P rearrangement triggered by protonation/deprotonation
 
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research article

Transformation between diphosphinoamines and iminobiphosphines: a reversible p-n-p <-> N=P-P rearrangement triggered by protonation/deprotonation

Fei, ZF  
•
Biricik, N
•
Zhao, DB  
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2004
Inorganic Chemistry

The protonation of diphosphinoamines attached to pyridine at the ortho-position quantitatively affords the corresponding iminobiphosphine isomers. The starting material can be recovered quantitatively by deprotonation with base. The system represents a new type of molecular switch.

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Type
research article
DOI
10.1021/ic049850w
Web of Science ID

WOS:000220583500003

Author(s)
Fei, ZF  
•
Biricik, N
•
Zhao, DB  
•
Scopelliti, R  
•
Dyson, PJ  
Date Issued

2004

Published in
Inorganic Chemistry
Volume

43

Issue

7

Start page

2228

End page

2230

Subjects

coordination

•

reactivity

•

phosphorus

•

analogs

•

acetonitrile

•

complexes

•

acceptor

•

basicity

•

ligands

•

salts

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
Available on Infoscience
November 9, 2005
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/219901
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