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research article
Transformation between diphosphinoamines and iminobiphosphines: a reversible p-n-p <-> N=P-P rearrangement triggered by protonation/deprotonation
2004
The protonation of diphosphinoamines attached to pyridine at the ortho-position quantitatively affords the corresponding iminobiphosphine isomers. The starting material can be recovered quantitatively by deprotonation with base. The system represents a new type of molecular switch.
Type
research article
Web of Science ID
WOS:000220583500003
Author(s)
Date Issued
2004
Published in
Volume
43
Issue
7
Start page
2228
End page
2230
Subjects
Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
November 9, 2005
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