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  4. Mitigation of Secondary Organic Aerosol Formation from Log Wood Burning Emissions by Catalytic Removal of Aromatic Hydrocarbons
 
research article

Mitigation of Secondary Organic Aerosol Formation from Log Wood Burning Emissions by Catalytic Removal of Aromatic Hydrocarbons

Pieber, Simone M.
•
Kambolis, Anastasios
•
Ferri, Davide
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November 20, 2018
Environmental Science & Technology

Log wood burning is a significant source of volatile organic compounds including aromatic hydrocarbons (ArHC). ArHC are harmful, are reactive in the ambient atmosphere, and are important secondary organic aerosol (SOA) precursors. Consequently, SOA represents a major fraction of the sub-micron organic aerosol pollution from log wood burning. ArHC reduction is thus critical in the mitigation of adverse health and environmental effects of log wood burning. In this study, two Pt-based catalytic converters were prepared and tested for the mitigation of real-world log wood burning emissions, including ArHC and SOA formation, as well as toxic carbon monoxide and methane, a greenhouse gas. Substantial removal of mono- and polycyclic ArHC and phenolic compounds was achieved with both catalysts operated at realistic chimney temperatures (50% conversion was achieved at 200 and 300 degrees C for non-methane hydrocarbons in our experiments for Pt/Al2O3 and Pt/CeO2-Al2O3, respectively). The catalytically cleaned emissions exhibited a substantially reduced SOA formation already at temperatures as low as 185-310 degrees C. This reduces the sub-micron PM burden of log wood burning significantly. Thus, catalytic converters can effectively reduce primary and secondary log wood burning pollutants and, thereby, their adverse health impacts and environmental effects.

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Type
research article
DOI
10.1021/acs.est.8b04124
Web of Science ID

WOS:000451245700047

Author(s)
Pieber, Simone M.
Kambolis, Anastasios
Ferri, Davide
Bhattu, Deepika
Bruns, Emily A.
Elsener, Martin
Krocher, Oliver  
Prevot, Andre S. H.
Baltensperger, Urs
Date Issued

2018-11-20

Publisher

AMER CHEMICAL SOC

Published in
Environmental Science & Technology
Volume

52

Issue

22

Start page

13381

End page

13390

Subjects

Engineering, Environmental

•

Environmental Sciences

•

Engineering

•

Environmental Sciences & Ecology

•

oxidation flow reactors

•

scale biomass combustion

•

room heating appliances

•

real-life operation

•

residential wood

•

particulate-emissions

•

chemical mechanism

•

radical chemistry

•

mass-spectrometry

•

rate coefficients

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-KRO  
Available on Infoscience
December 13, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/152547
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