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research article

Towards a two-step assessment of the chloride ingress behaviour of new cementitious binders

Wilson, William  
•
Georget, Fabien  
•
Scrivener, Karen L.  
October 1, 2024
Cement and Concrete Research

A wide range of systems were exposed to a seawater-like chloride concentration (0.5 M Cl−) for bulk diffusion experiments over 0.5, 1 and 4 years. Combined with previously published findings on chloride binding and mini-migration testing, the results showed that chloride ingress into saturated blended cement pastes is a diffusion-governed process, obeying the square root-law or a modified version including an offset to account for slow microstructure changes. Chloride ingress is also strongly correlated with bulk electrical conductivity, suggesting a negligible effect of chloride binding variations between the systems studied. These findings support a two-step approach to rapidly characterise the chloride ingress behaviour of new binders at the cement paste scale. A screening with bulk conductivity measurements investigates promising binders and the kinetics of their diffusion properties. In a second step, bulk diffusion tests and the square root law with an offset are used to predict chloride ingress.

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Type
research article
DOI
10.1016/j.cemconres.2024.107594
Scopus ID

2-s2.0-85197222737

Author(s)
Wilson, William  
•
Georget, Fabien  
•
Scrivener, Karen L.  
Date Issued

2024-10-01

Publisher

Pergamon-Elsevier Science Ltd

Published in
Cement and Concrete Research
Volume

184

Article Number

107594

Subjects

Blended cement paste

•

Bulk electrical conductivity

•

Chloride bulk diffusion

•

Square root law of diffusion

•

Supplementary cementitious materials

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMC  
FunderFunding(s)Grant NumberGrant URL

Fonds de recherche du Québec – Nature et technologies

Available on Infoscience
January 24, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/243488
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