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research article

Nanoparticle anisotropy induces sphere-to-cylinder phase transition in block copolymer melts

Diaz, Javier
•
Pinna, Marco
•
Zvelindovsky, Andrei
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May 6, 2022
Soft Matter

Block copolymer nanocomposites including anisotropic nanoparticles have been previously found to co-assemble into complex structures with nanoparticle alignment. Anisotropic nanoparticles with large aspect ratios are found to modify the morphology of block copolymers at modest concentrations, inducing a sphere-to-cylinder phase transition by breaking the local symmetry in the vicinity of a solid particle. This transition takes place over a wide range of NP lengths comparable with the BCP spacing. Controlling the orientation of uniaxial nanoparticles provides additional control over the global orientation of the block copolymer, as previously reported by experiments.

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Type
research article
DOI
10.1039/d2sm00214k
Web of Science ID

WOS:000791221500001

Author(s)
Diaz, Javier
Pinna, Marco
Zvelindovsky, Andrei
Pagonabarraga, Ignacio  
Date Issued

2022-05-06

Publisher

ROYAL SOC CHEMISTRY

Published in
Soft Matter
Volume

18

Issue

19

Start page

3638

End page

3643

Subjects

Chemistry, Physical

•

Materials Science, Multidisciplinary

•

Physics, Multidisciplinary

•

Polymer Science

•

Chemistry

•

Materials Science

•

Physics

•

nonuniform system

•

gold nanorods

•

free-energy

•

simulation

•

equilibrium

•

composites

•

morphology

•

mixtures

•

behavior

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC-GE  
Available on Infoscience
May 23, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/188042
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