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  4. Exploiting supramolecular assemblies for filterless ultra-narrowband organic photodetectors with inkjet fabrication capability
 
research article

Exploiting supramolecular assemblies for filterless ultra-narrowband organic photodetectors with inkjet fabrication capability

Anantharaman, Surendra B.
•
Strassel, Karen
•
Diethelm, Matthias
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December 14, 2019
Journal of Materials Chemistry C

Narrowband photodetectors are useful for a myriad of applications involving color discrimination as well as biological imaging and machine vision. Prevalent devices use broadband light absorbing materials in conjunction with electric (charge collection narrowing, photo multiplication) and optical strategies (optical cavity) to narrow down the spectral response of the detector. Here we exploit the intrinsic narrow absorption width of similar to 13-50 nm peculiar to J-aggregates of strongly coupled cyanine dye molecules for narrowband photodetectors. Albeit using ultrathin J-aggregate films (10 nm) the unparalleled optical aggregate properties lead to high external quantum efficiency (15%) and response speed (15 kHz) at low bias voltage (similar to 1 V). We show that the self-assembly process and device architecture used permit the incorporation of J-aggregates of various cyanine dyes with photodetection maxima ranging from the visible to the near-infrared region up to 1000 nm. Narrow bandwidth (o50 nm) photodetectors fabricated by inkjet printing the active device layers including the J-aggregate film perform on par with spin-coated devices, thus underlining their industrial potential.

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Type
research article
DOI
10.1039/c9tc04773e
Web of Science ID

WOS:000506638900023

Author(s)
Anantharaman, Surendra B.
Strassel, Karen
Diethelm, Matthias
Gubicza, Agnes
Hack, Erwin
Hany, Roland
Nuesch, Frank A.  
Heier, Jakob
Date Issued

2019-12-14

Publisher

Royal Society of Chemistry

Published in
Journal of Materials Chemistry C
Volume

7

Issue

46

Start page

14639

End page

14650

Subjects

Materials Science, Multidisciplinary

•

Physics, Applied

•

Materials Science

•

Physics

•

sensitized solar-cells

•

cyanine dyes

•

thin-films

•

light

•

nanoparticles

Editorial or Peer reviewed

REVIEWED

Written at

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January 25, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/164925
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