Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Pyroresistive response of percolating conductive polymer composites
 
research article

Pyroresistive response of percolating conductive polymer composites

Barbieri, Ettore
•
Bilotti, Emiliano
•
Liu, Yi
Show more
April 9, 2024
Physical Review Materials

The pyroresistive response of conductive polymer composites (CPCs) has attracted much interest because of its potential applications in many electronic devices requiring a significant responsiveness to changes in external physical parameters such as temperature or electric fields. Although extensive research has been conducted to study how the properties of the polymeric matrix and conductive fillers affect the positive temperature coefficient pyroresistive effect, the understanding of the microscopic mechanism governing such a phenomenon is still incomplete. In particular, to date, there is little body of theoretical research devoted to investigating the effect of the polymer thermal expansion on the electrical connectivity of the conductive phase. Here, we present the results of simulations of model CPCs in which rigid conductive fillers are dispersed in an insulating amorphous matrix. By employing a meshless algorithm to analyze the thermoelastic response of the system, we couple the computed strain field to the electrical connectedness of the percolating conductive particles. We show that the electrical conductivity responds to the local strains that are generated by the mismatch between the thermal expansion of the polymeric and conductive phases and that the conductor-insulator transition is caused by a sudden and global disconnection of the electrical contacts forming the percolating network.

  • Details
  • Metrics
Type
research article
DOI
10.1103/PhysRevMaterials.8.045602
Web of Science ID

WOS:001221821000003

Author(s)
Barbieri, Ettore
•
Bilotti, Emiliano
•
Liu, Yi
•
Grimaldi, Claudio  
Date Issued

2024-04-09

Publisher

Amer Physical Soc

Published in
Physical Review Materials
Volume

8

Issue

4

Article Number

045602

Subjects

Technology

•

Positive Temperature-Coefficient

•

Particle-Size Ratio

•

Continuum Percolation

•

Carbon-Black

•

Ptc

•

Resistivity

•

Behavior

•

Expansion

•

Threshold

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPM  
FunderGrant Number

Advanced Institute for Marine Ecosystem Change, World Premier International Research Center Initiative (WPI-AIMEC) of MEXT (Japan)

Available on Infoscience
June 5, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/208349
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés