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  4. Operando XAS study of the influence of CO and NO on methane oxidation by Pd/Al2O3
 
conference paper

Operando XAS study of the influence of CO and NO on methane oxidation by Pd/Al2O3

Marchionni, V.
•
Nachtegaal, M.
•
Petrov, A.
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2016
Proceedings of the 16th International Conference On X-Ray Absorption Fine Structure (Xafs16)
16th International Conference on X-ray Absorption Fine Structure (XAFS)

Methane oxidation on Pd/Al2O3 has been investigated using operando X-ray absorption spectroscopy (XAS) at the Pd K-edge. The influence of CO and NO on methane abatement has been addressed performing temperature programmed reaction runs while recording simultaneously XANES spectra. During CO oxidation Pd is reduced while methane conversion is shifted to higher temperature. NO strongly inhibits both CO and CH4 oxidation, despite the higher fraction of oxidized palladium.

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Type
conference paper
DOI
10.1088/1742-6596/712/1/012051
Web of Science ID

WOS:000383249000052

Author(s)
Marchionni, V.
Nachtegaal, M.
Petrov, A.
Krocher, O.  
Ferri, D.
Date Issued

2016

Publisher

Iop Publishing Ltd

Publisher place

Bristol

Published in
Proceedings of the 16th International Conference On X-Ray Absorption Fine Structure (Xafs16)
Total of pages

4

Series title/Series vol.

Journal of Physics Conference Series; 712

Volume

712

Start page

012051

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
GR-KRO  
Event nameEvent placeEvent date
16th International Conference on X-ray Absorption Fine Structure (XAFS)

Karlsruhe, Germany

23 - 28 August 2015

Available on Infoscience
January 24, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/133876
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