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  4. Stability Of Magnesite (MgCO3) At Mantle Pressure And Temperature Conditions - A Raman-Spectroscopic Study
 
research article

Stability Of Magnesite (MgCO3) At Mantle Pressure And Temperature Conditions - A Raman-Spectroscopic Study

Gillet, Philippe  
1993
American Mineralogist

The stability of magnesite (MgCO3) has been studied by Raman spectroscopy at high pressure and high temperature using a diamond-anvil cell heated by a CO2 laser. Raman spectra up to 32 GPa at room temperature unambiguously confirm that under quasi-hydrostatic conditions, unlike CaCO3, magnesite does not undergo phase transitions. Raman spectra recorded at simultaneous high pressure (26 GPa) and high temperature (1200 +/- 200 K) show that under these conditions magnesite retains its ambient R3cBAR structure. Optical observations during heating, as well as Raman spectra recorded at 30 GPa after laser heating up to 2000-2500 K, show that no decarbonation has occurred and that magnesite is stable. All these results are in agreement with other experimental data and show that magnesite can act as a host for C storage down to at least 1000 km and can also be the carrier for C in subducting plates.

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Type
research article
Author(s)
Gillet, Philippe  
Date Issued

1993

Publisher

Mineralogical Society of America

Published in
American Mineralogist
Volume

78

Start page

1328

End page

1331

Subjects

Phase-Relations

•

Carbonate

•

System

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
EPSL  
Available on Infoscience
September 29, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/71377
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