Stress Engineering for Mitigating Thermal Cycling Fatigue in Perovskite Photovoltaics
Mechanical residual stresses within multilayer thin-film device stacks become problematic during thermal changes because of differing thermal expansion and contraction of the various layers. Thin-film photovoltaic (PV) devices are a prime example where this is a concern during temperature fluctuations that occur over long deployment lifetimes. Here, we show control of the residual stress within halide perovskite thin-film device stacks by the use of an alkyl-ammonium additive. This additive approach reduces the residual stress and strain to near-zero at room temperature and prevents cracking and delamination during intense and rapid thermal cycling. We demonstrate this concept in both n-i-p (regular) and p-i-n (inverted) unencapsulated perovskite solar cells and minimodules with both types of solar cells retaining over 80% of their initial power conversion efficiency (PCE) after 2500 thermal cycles in the temperature range of -40 to 85°C. The mechanism by which stress engineering mitigates thermal cycling fatigue in these perovskite PVs is discussed.
WOS:001225132100001
2024-05-08
REVIEWED
EPFL
Funder | Grant Number |
Office of Naval Research | |
National Renewable Energy Laboratory | DE-AC36-08GO28308 |
U.S. Department of Energy (DOE) | |
Operational Energy Capability Improvement Fund (OECIF) of the U.S. Department of Defense (DOD) | |
Center for Hybrid Organic Inorganic Semiconductors for Energy - Office of Basic Energy Sciences, Office of Science, within the US Department of Energy | N00014-20-1-2573 |
Office of Naval Research (ONR) | N00014-20-1-2574 |
ONR | |