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  4. Activation of stainless steel 316L anode for anion exchange membrane water electrolysis
 
research article

Activation of stainless steel 316L anode for anion exchange membrane water electrolysis

Sampathkumar, S. Nuggehalli
•
Ferriday, T. B.
•
Middleton, P. H.
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December 22, 2022
Electrochemistry Communications

The increased emphasis on renewable energy has resulted in a surge of R&D efforts into hydrogen and battery research. The intensive electrochemical environment surrounding the anodic oxygen evolution reaction (OER) has plagued both the activity and stability of the catalytic layer, substrate and porous transport layer, ultimately affecting both these industries. Herein, we report the benefits of potential cycling (PC) a 316L stainless steel felt porous transport layer (PTL) for use in anion exchange membrane water electrolysis. The PC increased surface roughness and created a CrFe5Ni2-OxHy layer through the oxidation of iron as shown by SEM, EDS, XPS, XRD and Raman spectroscopy. Post-PC tests in a three-electrode setup reveal a approximate to 68% decline in polarisation resistance, which is reflected in its performance when employed as an anode in an anion exchange membrane water electrolyser (AEMWE). Overall, potential cycling the PTL under anodic conditions resulted in an improved performance when tested in a AEMWE. Implementing this treatment on stainless steel anodes could be considered to achieve an improved AEMWE performance.

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Type
research article
DOI
10.1016/j.elecom.2022.107418
Web of Science ID

WOS:000920452300001

Author(s)
Sampathkumar, S. Nuggehalli
Ferriday, T. B.
Middleton, P. H.
Van Herle, J.  
Date Issued

2022-12-22

Publisher

ELSEVIER SCIENCE INC

Published in
Electrochemistry Communications
Volume

146

Article Number

107418

Subjects

Electrochemistry

•

anode

•

porous transport layer

•

oxygen evolution reaction

•

316l stainless steel

•

anion exchange membrane water electrolysis

•

potential cycling

•

electrochemical impedance spectroscopy

•

nifecr hydroxide

•

evolution

•

ni

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electrocatalyst

•

oxidation

•

films

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-STI-JVH  
Available on Infoscience
February 27, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/195163
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