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  4. Electrochemical comparison between IrO2 prepared by thermal treatment of iridium metal and IrO2 prepared by thermal decomposition of H2IrCl6 solution
 
research article

Electrochemical comparison between IrO2 prepared by thermal treatment of iridium metal and IrO2 prepared by thermal decomposition of H2IrCl6 solution

Fierro, S.  
•
Kapalka, A.  
•
Comninellis, Ch.  
2010
Electrochemistry Communications

The surface redox activities, the oxygen evolution reaction (OER), the oxidation of formic acid (FA) and the anodic stability have been investigated and compared on IrO2 electrodes prepared by two techniques: the thermal decomposition of H2IrCl6 precursor (TDIROF) and the thermal treatment of metallic iridium (TOIROF). It was found, that the surface redox activities involved on both IrO2-based electrodes are similar. Concerning the oxygen evolution reaction and the oxidation of formic acid, both films show similar mechanism.

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Type
research article
DOI
10.1016/j.elecom.2009.11.018
Web of Science ID

WOS:000274233700043

Author(s)
Fierro, S.  
Kapalka, A.  
Comninellis, Ch.  
Date Issued

2010

Publisher

Elsevier

Published in
Electrochemistry Communications
Volume

12

Start page

172

End page

174

Subjects

IrO2

•

Thermal decomposition of H2IrCl6

•

Thermal treatment of metallic Ir

•

Oxygen evolution

•

Formic acid oxidation

•

Surface redox activity

•

Oxygen Evolution Reaction

•

Formic-Acid Oxidation

•

Ti/Iro2 Electrodes

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GGEC  
Available on Infoscience
November 19, 2009
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/44301
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