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research article

Helical interfacial modulation for perovskite photovoltaics

Alsabeh, Ghewa  
•
Almalki, Masaud
•
Kasemthaveechok, Sitthichok
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May 30, 2024
Nanoscale Advances

Hybrid metal halide perovskites have demonstrated remarkable performances in modern photovoltaics, although their stabilities remain limited. We assess the capacity to advance their properties by relying on interfacial modulators featuring helical chirality based on P,M-(1-methylene-3-methyl-imidazolium)[6]helicene iodides. We investigate their characteristics, demonstrating comparable charge injection for enantiomers and the racemic mixture. Overall, they maintain the resulting photovoltaic performance while improving operational stability, challenging the role of helical chirality in the interfacial modulation of perovskite solar cells.|Helical modulators improve the operational stability of perovskite solar cells without a significant effect on photovoltaic characteristics, challenging the role of chiral interfacial modulators in hybrid perovskite photovoltaics.

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Type
research article
DOI
10.1039/d4na00027g
Web of Science ID

WOS:001234997800001

Author(s)
Alsabeh, Ghewa  
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Almalki, Masaud
•
Kasemthaveechok, Sitthichok
•
Ruiz-Preciado, Marco A.  
•
Zhang, Hong  
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Vanthuyne, Nicolas
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Zimmermann, Paul
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Dekker, Daphne M.
•
Eickemeyer, Felix Thomas  
•
Hinderhofer, Alexander
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Date Issued

2024-05-30

Publisher

Royal Soc Chemistry

Published in
Nanoscale Advances
Volume

6

Issue

12

Start page

3029

End page

3033

Subjects

Physical Sciences

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Technology

•

Induced Spin Selectivity

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Hybrid Perovskite

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Efficient

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Semiconductors

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Degradation

•

Migration

•

Enables

•

Impact

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
FunderGrant Number

Schweizerischer Nationalfonds zur Frderung der Wissenschaftlichen Forschung

764047

European Union's Horizon 2020 Research and Innovation Program

193174

SNSF

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Available on Infoscience
June 19, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/208686
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