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research article

Electronic Spectroscopy of Aniline Ions Embedded in Helium Nanodroplets

Brauer, Nils Benedict  
•
Smolarek, Szymon
•
Zhang, Xiaohang  
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2011
The Journal of Physical Chemistry Letters

Excitation spectra of the and transitions of aniline cations embedded in helium nanodroplets are reported. The spectra are characterized by broad asymmetric resonances that consist of an intrinsically broadened zero-phonon line which partially overlaps with the accompanying phonon wing. The band origin of the transition reveals a blue-shift of 116±84 cm-1 with respect to the corresponding gas phase transition. This blue-shift is suggested to be related to the presence of a relatively strongly bound high-density helium solvation layer around the ion.

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Type
research article
DOI
10.1021/jz200632s
Web of Science ID

WOS:000292893400013

Author(s)
Brauer, Nils Benedict  
•
Smolarek, Szymon
•
Zhang, Xiaohang  
•
Buma, Wybren Jan
•
Drabbels, Marcel  
Date Issued

2011

Published in
The Journal of Physical Chemistry Letters
Volume

2

Article Number

1563

Subjects

helium nanodroplets

•

electronic spectroscopy

•

aniline

•

cation

•

superfluidity

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
June 4, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/68134
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