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  4. Charge Gradients around Dendritic Voids Cause Nanoscale Inhomogeneities in Liquid Water
 
research article

Charge Gradients around Dendritic Voids Cause Nanoscale Inhomogeneities in Liquid Water

Schoenfeldova, Tereza  
•
Dupertuis, Nathan  
•
Chen, Yixing  
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August 5, 2022
The Journal of Physical Chemistry Letters

Water is the matrix of life and serves as a solvent for numerous physical and chemical processes. The origins of the nature of inhomogeneities that exist in liquid water and the time scales over which they occur remains an open question. Here, we report femtosecond elastic second harmonic scattering (fs-ESHS) of liquid water in comparison to an isotropic liquid (CCl4) and show that water is indeed a nonuniform liquid. The coherent fs-ESHS intensity was interpreted, using molecular dynamics simulations, as arising from charge density fluctuations with enhanced nanoscale polarizabilities around transient voids having an average lifetime of 300 fs. Although voids were also present in CCl4, they were not characterized by hydrogen bond defects and did not show strong polarizability fluctuations, leading to fs-ESHS of an isotropic liquid. The voids increased in number at higher temperatures above room temperature, in agreement with the fs-ESHS results.

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Type
research article
DOI
10.1021/acs.jpclett.2c01872
Web of Science ID

WOS:000844612900001

Author(s)
Schoenfeldova, Tereza  
Dupertuis, Nathan  
Chen, Yixing  
Ansari, Narjes
Poli, Emiliano
Wilkins, David M.
Hassanali, Ali
Roke, Sylvie  
Date Issued

2022-08-05

Publisher

AMER CHEMICAL SOC

Published in
The Journal of Physical Chemistry Letters
Volume

13

Issue

32

Start page

7462

End page

7468

Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Atomic, Molecular & Chemical

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

hydrogen-bond network

•

light-scattering

•

spectroscopy

•

dynamics

•

order

•

frequency

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

Available on Infoscience
September 12, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/190705
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