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  4. Effect of Different Hole Transport Materials on Recombination in CH3NH3PbI3 Perovskite-Sensitized Mesoscopic Solar Cells
 
research article

Effect of Different Hole Transport Materials on Recombination in CH3NH3PbI3 Perovskite-Sensitized Mesoscopic Solar Cells

Bi, Dongqin  
•
Yang, Lei
•
Boschloo, Gerrit
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2013
The Journal of Physical Chemistry Letters

We report on perovskite (CH3NH3)PbI3-sensitized solid-state solar cells using spiro-OMeTAD, poly(3-hexylthiophene-2,5-diyl) (P3HT) and 4-(diethylamino)benzaldehyde diphenylhydrazone (DEH) as hole transport materials with a light to electricity power conversion efficiency of 8.5%, 4.5%, and 1.6%, resp., under AM 1.5G illumination of 1000 W/m2 intensity. Photoinduced absorption spectroscopy shows that hole transfer occurs from the (CH3NH3)PbI3 to hole transport materials after excitation of (CH3NH3)PbI3. The electron lifetime (τe) in these devices are in the order Spiro-OMeTAD > P3HT > DEH, while the charge transport time (ttr) is rather similar. The difference in τe can therefore explain the lower efficiency of the devices based on P3HT and DEH. This report shows that the nature of the hole transport material is essential for charge recombination and elucidates that finding an optimal hole transport material for the perovskite solar cell includes controlling the perovskite/hole transport material interaction. Design routes for new hole transport materials are suggested.

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Type
research article
DOI
10.1021/jz400638x
Author(s)
Bi, Dongqin  
Yang, Lei
Boschloo, Gerrit
Hagfeldt, Anders  
Johansson, Erik M. J.
Date Issued

2013

Published in
The Journal of Physical Chemistry Letters
Volume

4

Start page

1532

End page

1536

Subjects

hole transport material methylammonium iodoplumbate sensitized solar cell recombination

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115872
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