Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Bulk Defects and Hydrogenation Kinetics in Crystalline Silicon Solar Cells With Fired Passivating Contacts
 
research article

Bulk Defects and Hydrogenation Kinetics in Crystalline Silicon Solar Cells With Fired Passivating Contacts

Lehmann, Mario  
•
Desthieux, Anatole
•
Valle, Nathalie
Show more
April 11, 2022
Ieee Journal Of Photovoltaics

In this article, the effect of the various processing steps during the fabrication of c-Si/SiOx/SiCx fired passivating contacts on the silicon bulk lifetime is studied, and the kinetics of defect deactivation by hydrogenation is investigated. It is found that the firing step at 800 degrees C induces shallow bulk defects in float-zone silicon wafers, which can subsequently be passivated with hydrogen provided by an a-SiNx:H/D reservoir layer upon annealing at 450 degrees C. Experimental results and numerical data treatment indicate a rapid passivation of the surface within less than 1 min, followed by a slower passivation of the shallow bulk defects. In situ lifetime measurements are consistent with a slow bulk lifetime improvement by showing similar lifetime evolutions for both p-type and n-type SiCx layers. The kinetics of the hydrogenation process seems to be limited by the available hydrogen supply at the c-Si/SiOx interface, rather than by its diffusion within the bulk of the wafer. Moreover, it is affected by the bulk doping as well as the SiCx layer thickness. Finally, it is shown that hydrogenation is also possible with an a-SiNx:H/D reservoir layer deposited on one side of the wafer only, although resulting in a lower passivation level (s similar to 700 mu s compared to similar to 1300 mu s for symmetrical samples), and slower kinetics (similar to 5 min compared to similar to 0.8 min).

  • Files
  • Details
  • Metrics
Loading...
Thumbnail Image
Name

Lehmann-2022jpv-postprint.pdf

Type

Postprint

Version

http://purl.org/coar/version/c_ab4af688f83e57aa

Access type

openaccess

License Condition

copyright

Size

854.17 KB

Format

Adobe PDF

Checksum (MD5)

6a9e088cfa0a63010641356f2080f29d

Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés