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research article

Ferroelectric Self-Poling in GeTe Films and Crystals

Kriegner, Dominik
•
Springholz, Gunther
•
Richter, Carsten
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June 28, 2019
Crystals

Ferroelectric materials are used in actuators or sensors because of their non-volatile macroscopic electric polarization. GeTe is the simplest known diatomic ferroelectric endowed with exceedingly complex physics related to its crystalline, amorphous, thermoelectric, and—fairly recently discovered—topological properties, making the material potentially interesting for spintronics applications. Typically, ferroelectric materials possess random oriented domains that need poling to achieve macroscopic polarization. By using X-ray absorption fine structure spectroscopy complemented with anomalous diffraction and piezo-response force microscopy, we investigated the bulk ferroelectric structure of GeTe crystals and thin films. Both feature multi-domain structures in the form of oblique domains for films and domain colonies inside crystals. Despite these multi-domain structures which are expected to randomize the polarization direction, our experimental results show that at room temperature there is a preferential ferroelectric order remarkably consistent with theoretical predictions from ideal GeTe crystals. This robust self-poled state has high piezoelectricity and additional poling reveals persistent memory effects.

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Type
research article
DOI
10.3390/cryst9070335
Author(s)
Kriegner, Dominik
Springholz, Gunther
Richter, Carsten
Pilet, Nicolas
Müller, Elisabeth
Capron, Marie
Berger, Helmut
Holý, Václav
Dil, J. Hugo
Krempaský, Juraj
Date Issued

2019-06-28

Published in
Crystals
Volume

9

Issue

7

Start page

335

Subjects

self-polarization

•

ferroelectricity

•

microstructure

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EXAFS

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PFM

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anomalous diffraction

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thin films

•

single crystals

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-SB-HD  
Available on Infoscience
July 22, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/159284
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