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  4. Kinetic study of formic acid oxidation on Ti/IrO2 electrodes prepared using the spin coating deposition technique
 
research article

Kinetic study of formic acid oxidation on Ti/IrO2 electrodes prepared using the spin coating deposition technique

Fierro, S.  
•
Comninellis, Ch.  
2010
Electrochimica Acta

In the first part of this paper, IrO2 electrodes produced by thermal decomposition of H2IrCl6 precursor were manufactured using the spin coating deposition technique, where centrifugal forces spread the precursor solution with simultaneous evaporation of the solvent on the rotating Ti substrate. It was found using this technique, that it is possible to obtain thin and uniform IrO2 coatings with controlled loadings. The influence of the concentration of iridium salt in the precursor solution (c(0)) as well as the influence of the rotation speed at which the substrate spins (omega) on the IrO2 loading have been studied using voltammetric charge measurements. From these results, a simple relation has been proposed for the estimation of the IrO2 loading for a given c(0) and omega.

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Type
research article
DOI
10.1016/j.electacta.2010.06.066
Web of Science ID

WOS:000281994700021

Author(s)
Fierro, S.  
Comninellis, Ch.  
Date Issued

2010

Publisher

Elsevier

Published in
Electrochimica Acta
Volume

55

Start page

7067

End page

7073

Subjects

IrO2 electrodes

•

Spin coating

•

Voltammetric charge

•

Formic acid oxidation

•

Kinetic parameters

•

Waste-Water Treatment

•

Anodic-Oxidation

•

Mass

•

Phenol

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GGEC  
Available on Infoscience
July 1, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/51415
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