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research article

Electric-field-, temperature-, and stress-induced phase transitions in relaxor ferroelectric single crystals

Davis, M.  
•
Damjanovic, D.  
•
Setter, N.  
2006
Physical Review B

Electric-field-induced phase transitions have been evidenced by macroscopic strain measurements at temperatures between 25 degrees C and 100 degrees C in 001-poled (1-x)Pb(Mg1/3Nb2/3)O-3-xPbTiO(3) [(PMN-xPT);x=0.25,0.305,0.31] and (1-x)Pb(Zn1/3Nb2/3)O-3-xPbTiO(3) [(PZN-xPT);x=0.05,0.065,0.085] single crystals. Such measurements provide a convenient way of ascertaining thermal and electrical phase stabilities over a range of compositions and give direct evidence for first-order phase transitions. A pseudorhombohedral (M-A)-pseudo-orthorhombic (M-C)-tetragonal (T) polarization rotation path is evidenced by two first-order-like, hysteretic discontinuities in strain within the same unipolar electric field cycle for PZN-5PT, PMN-30.5PT, and PMN-31PT whereas, in PMN-25PT, a single first-order-like M-A-T transition is observed. This agrees well with in situ structural studies reported elsewhere. Electric-field-temperature (E-T) phase diagrams are constructed showing general trends for M-A, M-C, and T phase stabilities for varying temperatures and electric fields in poled samples over the given range of compositions. The complex question of whether the M-A and M-C states constitute true phases, or rather piezoelectrically distorted versions of their rhombohedral (R) and orthorhombic (O) parents, is discussed. Finally, stress-induced phase transitions are evidenced in 001-poled PZN-4.5PT by application of a moderate compressive stress (< 100 MPa) both along and perpendicularly to the poling direction (longitudinal and transverse modes, respectively). The rotation path is likely R-M-B-O, via a first-order, hysteretic rotation within the M-B monoclinic plane. The results are presented alongside a thorough review of previously reported electric-field-induced and stress-induced phase transitions in PMN-xPT and PZN-xPT.

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Type
research article
DOI
10.1103/PhysRevB.73.014115
Web of Science ID

WOS:000235009000051

Author(s)
Davis, M.  
Damjanovic, D.  
Setter, N.  
Date Issued

2006

Published in
Physical Review B
Volume

73

Issue

1

Article Number

014115

Subjects

x-ray-diffraction

•

piezoelectric properties

•

monoclinic phase

•

barium-titanate

•

solid-solution

•

0.7pb(mg1/3nb2/3)o-3-0.3pbtio(3) crystals

•

electromechanical response

•

pyroelectric properties

•

domain configurations

•

polarization rotation

Note

Davis, M Ecole Polytech Fed Lausanne, Ceram Lab, Lausanne, Switzerland Ecole Polytech Fed Lausanne, Ceram Lab, Lausanne, Switzerland

007ZC

Cited References Count:77

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233585
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