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  4. Design and implementation of a soft X-ray absorption spectroscopy setup for liquid samples at SwissFEL
 
doctoral thesis

Design and implementation of a soft X-ray absorption spectroscopy setup for liquid samples at SwissFEL

Knurr, Jonas  
2024

This thesis presents the development and implementation of a novel experimental setup for time-resolved soft X-ray absorption spectroscopy on liquid samples at SwissFEL. The setup allows the investigation of important absorption edges, such as the nitrogen K-edge, the oxygen K-edge and transition metal L-edges, for site-selective studies of a sample in a single experiment. A key feature of the setup is a novel catcher design in combination with a gas-squeezing liquid jet. This allows the reliable use of liquid sheets of adjustable thickness in a high vacuum environment adhering to the requirements of experiments at free-electron laser sources. The setup can be operated with small sample volumes of 50 mL , and recircula- tion of the sample is possible. Test experiments at a synchrotron light source provided first valence absorption spectra of liquid water. At the X-ray free-electron laser, proof-of-concept experiments yielded absorption spectra of water around the oxygen K-edge and the transient absorption of a 30 mM aqueous iron(II)-trisbipyridine solution around the nitrogen K-edge and the iron L3-edge. Different modalities for X-ray absorption measurements with intense pulses from a free-electron laser were compared and recommendations depending on the sample conditions were formulated.

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Type
doctoral thesis
DOI
10.5075/epfl-thesis-10809
Author(s)
Knurr, Jonas  

EPFL

Advisors
Bostedt, Christoph  
Jury

Prof. Andreas Osterwalder (président) ; Prof. Christoph Bostedt (directeur de thèse) ; Prof. Rainer Beck, Prof. Malte Oppermann, Prof. Andrea Cannizzo (rapporteurs)

Date Issued

2024

Publisher

EPFL

Publisher place

Lausanne

Public defense year

2024-10-29

Thesis number

10809

Total of pages

165

Subjects

X-ray absorption

•

time-resolved

•

liquid jet

•

free-electron laser

EPFL units
LUXS  
Faculty
SB  
School
ISIC  
Doctoral School
EDCH  
Available on Infoscience
October 21, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/241659
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