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  4. Development of Ti-Zr-Mn based AB 2 type metal hydrides alloys for an 865 bar two-stage hydrogen compressor
 
research article

Development of Ti-Zr-Mn based AB 2 type metal hydrides alloys for an 865 bar two-stage hydrogen compressor

Li, Rui
•
Penmathsa, Akhil  
•
Sun, Tai
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June 27, 2024
International Journal Of Hydrogen Energy

This study reports the development of a new Ti-Zr-Mn-based AB 2 type hydrogen storage alloys for a two-stage metal hydride hydrogen compressor (MHHC). The hydrogen storage alloys are designed to compress hydrogen from 35 to 865 bar within a temperature difference of 115 degrees C. High-pressure PCT measurements up to 700 bar were carried out to test the performance of the alloys. The alloys ' hysteresis and the plateau slope were reduced by optimizing the composition. The introduction of fugacity correction into the Van ' t hoff equation reduces the deviation between calculation and actual pressure to 24 bar at a pressure above 350 bar. A precise relation between the Ti/Zr ratio and the desorption pressure is described and helps make a correct design of the alloy composition. The designed alloy shows looses less than 1% of the capacity over 3000 full cycles. The desorption plateau pressure of the alloy is constant within 92% during the whole cycling process. A 2 stages compressor working with two types of alloys offers compression with a temperature range between -20 and 95 degrees C for the refueling hydrogen vehicles up to 865 bar.

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Type
research article
DOI
10.1016/j.ijhydene.2024.05.336
Web of Science ID

WOS:001249669800004

Author(s)
Li, Rui
Penmathsa, Akhil  
Sun, Tai
Gallandat, Noris
Li, Jinyu
Park, Jihye
Kim, Han-Jin
Kim, Pyungsoon
Yoon, Narae
Jang, Ji-Hoon
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Date Issued

2024-06-27

Publisher

Pergamon-Elsevier Science Ltd

Published in
International Journal Of Hydrogen Energy
Volume

72

Start page

687

End page

693

Subjects

Physical Sciences

•

Technology

•

Metal Hydrides

•

Hydrogen Compressor

•

Hydrogen Compression

•

Hydrogen Storage

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Cycle Stability

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Hydrogen Refueling Station

Editorial or Peer reviewed

REVIEWED

Written at

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July 3, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/209113
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