Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Elementary Excitations of Superfluid Helium Droplets Probed by Ion Spectroscopy
 
Loading...
Thumbnail Image
research article

Elementary Excitations of Superfluid Helium Droplets Probed by Ion Spectroscopy

Zhang, Xiaohang  
•
Drabbels, Marcel  
2014
The Journal of Physical Chemistry Letters

Electronic spectra of molecules in helium droplets reveal spectral features that are related to the elementary excitations of the superfluid helium environment. In order to determine to what extend the interaction strength of the molecule with the helium affects these excitations, the spectrum corresponding to the transition of 2,5-difluorophenol cations in a helium droplets has been recorded. The vibronic resonances reveal a sharp zero-phonon line whose width is largely determined by the rotational band contour, followed by a broad structureless phonon wing at higher frequencies. The splitting between the zero-phonon line and phonon wing is approximately half that found for neutral 2,5-difluorophenol. This difference is attributed to the increased helium density around the ion due to its strong interaction with the helium.

  • Details
  • Metrics
Type
research article
DOI
10.1021/jz501530e
Web of Science ID

WOS:000343067700006

Author(s)
Zhang, Xiaohang  
•
Drabbels, Marcel  
Date Issued

2014

Publisher

Amer Chemical Soc

Published in
The Journal of Physical Chemistry Letters
Volume

18

Article Number

3100

Subjects

superfluidity

•

dispersion relation

•

zero-phonon line

•

phonon wing

•

2

•

5- difluorophenol

•

cation

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
August 27, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/106062
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés