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  4. Influence of Ir Additions and Icosahedral Short Range Order (ISRO) on Nucleation and Growth Kinetics in Au-20.5Wt Pct Cu-4.5Wt PctAg Alloy
 
research article

Influence of Ir Additions and Icosahedral Short Range Order (ISRO) on Nucleation and Growth Kinetics in Au-20.5Wt Pct Cu-4.5Wt PctAg Alloy

Zollinger, J.
•
Rouat, B.
•
Guyon, J.
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May 1, 2019
Metallurgical And Materials Transactions A-Physical Metallurgy And Materials Science

Based on detailed EBSD analyses, Kurtuldu et al. (Acta Mater. 70:240-248, 2014) have explained the grain refinement of Au-12.5 wt pctCu-12.5 wt pctAg (yellow gold) by the addition of minute amounts of Ir in terms of icosahedral quasicrystal (iQC)-mediated nucleation, i.e., Ir induced the formation of Icosahedral short range order (ISRO) of atoms in the liquid, leading to the formation of iQC on which the fcc-phase forms. In the present contribution, we show that: (i) this mechanism is also responsible of the grain refinement in Au-20.5 wt pctCu-4.5 wt pctAg (pink gold) with Ir addition; (ii) ISRO also influences the morphology and growth kinetics of the fcc phase: at solidification rate of a few mm/s, 100 dendrites are replaced by a cellular-type morphology growing along 111 when 100 wt ppm of Ir is added to the melt; (iii) iQC-mediated nucleation is accompanied by a spinodal decomposition of the liquid, which is revealed at high cooling rate by the formation of Cu-rich particles or dendrites, some of them being also twinned, in parallel to iQC-mediated grain refinement and twin formation. (C) The Minerals, Metals & Materials Society and ASM International 2019

  • Details
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Type
research article
DOI
10.1007/s11661-019-05176-2
Web of Science ID

WOS:000463991300018

Author(s)
Zollinger, J.
Rouat, B.
Guyon, J.
Pillai, S. K.
Rappaz, M.  
Date Issued

2019-05-01

Publisher

SPRINGER

Published in
Metallurgical And Materials Transactions A-Physical Metallurgy And Materials Science
Volume

50

Issue

5

Start page

2279

End page

2288

Subjects

Materials Science, Multidisciplinary

•

Metallurgy & Metallurgical Engineering

•

Materials Science

•

Metallurgy & Metallurgical Engineering

•

crystal-enhanced nucleation

•

quasi-crystal

•

dendrites

•

morphologies

•

system

•

phase

•

al

•

cr

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSMX  
Available on Infoscience
June 18, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/157240
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