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  4. Localized Tunneling 1D Perovskitoid Passivated Contacts for Efficient and Stable Perovskite Solar Modules
 
research article

Localized Tunneling 1D Perovskitoid Passivated Contacts for Efficient and Stable Perovskite Solar Modules

Wang, Qian
•
Zhang, Kai  
•
Ding, Weifan
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2025
Advanced Energy Materials

Interface engineering has proven to be an effective approach for passivating interfacial imperfections to mitigate non-radiative recombination, but the subpar interface quality between the perovskite and the charge transport layer has hindered advancements in charge extraction and transport. Herein, localized tunneling passivated contacts are presented using self-assembled one-dimensional (1D) perovskitoid through an in situ reaction between1-ethyl-2-methylpyridinium iodide ([EtMePy]I) and PbI2. The formation of a uniform conformal layer and a non-continuous distribution of 1D [EtMePy]PbI3 perovskitoid crystals serves as a localized tunneling contact at the interface between the perovskite and the hole transport layer, which suppresses interfacial non-radiative recombination and facilitates spatial separation of carriers. The optimized perovskite solar modules achieve a power conversion efficiency of 22.54% and a high fill factor of 80.0% with an aperture area of 29.0 cm2. The encapsulated device retains 90.4% of its initial PCE after ≈1,000 h of maximum power point tracking at 85 °C and 85% relative humidity (RH) under 1.0 Sun illumination.

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Type
research article
DOI
10.1002/aenm.202405133
Scopus ID

2-s2.0-105000828856

Author(s)
Wang, Qian

University of Science and Technology Beijing

Zhang, Kai  

École Polytechnique Fédérale de Lausanne

Ding, Weifan

University of Science and Technology Beijing

He, Yuhua

University of Science and Technology Beijing

Chen, Xiaohan

Hohai University

Tian, Yuan

Westlake University

Li, Zerui

University of Science and Technology Beijing

Ding, Bin

École Polytechnique Fédérale de Lausanne

Alshahrani, Thamraa

Princess Nourah Bint Abdulrahman University

Wang, Rui

Westlake University

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Date Issued

2025

Published in
Advanced Energy Materials
Subjects

charge extraction

•

charge recombination

•

perovskite solar cell

•

stability

•

TOPCon

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
FunderFunding(s)Grant NumberGrant URL

National Natural Science Foundation of China

22279033

National Key Research and Development Program of China

2023YFB4204502

111 Project

B16016

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Available on Infoscience
April 7, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/248717
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