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research article

Fabrication of metallic nanoparticles by electrochemical discharges

Lal, A.  
•
Bleuler, H.  
•
Wuethrich, R.
2008
Electrochemistry Communications

A method for the fabrication of metallic nanoparticles in large quantities by electrochemical discharges is presented. In an aqueous electrolyte, large current density (similar to 1 A/mm(2) at similar to 20 V) leads to the formation of a 'gas film' around the electrode through which discharges occur. When metal ions are additionally present in the electrolyte and when the applied potential is cathodic, metal nanoparticles (typically 10-150 nm) are produced. The nanoparticles are formed in the solution and the gas film prevents them from depositing on the electrode. To control the size of the particles a method based on 'rotating electrode' is developed. Rotating the cathode rotates the fluid around it, which provides centrifugal force to the particles to move away from the electrode where they cannot grow. This method has been successfully used for fabrication of nanoparticles from several metal salts. (c) 2008 Elsevier B.V. All rights reserved.

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Type
research article
DOI
10.1016/j.elecom.2008.01.017
Web of Science ID

WOS:000254190800030

Author(s)
Lal, A.  
Bleuler, H.  
Wuethrich, R.
Date Issued

2008

Publisher

Elsevier

Published in
Electrochemistry Communications
Volume

10

Start page

488

End page

491

Subjects

nanoparticle

•

electrochemical discharges

•

Electrodes

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSRO  
Available on Infoscience
November 30, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/61523
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