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  4. Decoupling light absorption and charge transport properties in near IR-sensitized Fe2O3 regenerative cells
 
research article

Decoupling light absorption and charge transport properties in near IR-sensitized Fe2O3 regenerative cells

Kumar, Mulmudi Hemant
•
Mathews, Nripan
•
Boix, Pablo P.
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2013
Energy & Environmental Science

We report a regenerative iron oxide nanorod solar cell sensitized with squarine (SQ02) dye, which improves the overall light harvesting due to the dye's complementary absorption. The use of illumination sources which enabled selective excitation of Fe2O3 and the dye independently allowed the decoupling of transport and light absorption in Fe2O3. From absorbed photon-to-current conversion efficiency (APCE) calculations, it was found out that about 80% (at lambda = 680 nm) of the absorbed photons in SQ02 dye are converted to electrons and transported without any further loss into the FTO electrode. Impedance spectroscopy revealed that bulk recombination is still a prominent problem while utilizing hematite as a photoanode in a dye sensitized configuration.

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Type
research article
DOI
10.1039/c3ee42438c
Web of Science ID

WOS:000325946400017

Author(s)
Kumar, Mulmudi Hemant
Mathews, Nripan
Boix, Pablo P.
Nonomura, Kazuteru
Powar, Satvasheel
Ming, Lam Yeng
Graetzel, Michael  
Mhaisalkar, Subodh G.
Date Issued

2013

Publisher

Royal Society of Chemistry

Published in
Energy & Environmental Science
Volume

6

Issue

11

Start page

3280

End page

3285

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
December 9, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/97664
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