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  4. Charge storage at Pt/YSZ interface as the origin of 'permanent' electrochemical promotion of catalysis
 
research article

Charge storage at Pt/YSZ interface as the origin of 'permanent' electrochemical promotion of catalysis

Foti, Gyoergy  
2009
Periodica Polytechnica-Chemical Engineering

Tuning of the catalytic reaction rate by electric polarization of the interface between an electron conducting catalyst and an ion conducting support, called electrochemical promotion of catalysis (EPOC), is most often fully reversible. Its state-of-the-art model regards the gas-exposed catalyst surface as the unique location of charge storage via backspillover of electrochemically generated species, responsible for promotion. After long-lasting anodic polarization, a permanent effect (P-EPOC) was observed in ethylene combustion with oxygen over Pt/YSZ catalyst. Double step chronoamperometric and linear sweep voltammetric analysis revealed delayed oxygen storage, located presumably at the vicinity of the catalyst/electrolyte interface. It is proposed that oxygen stored at this location, hence hidden for the reactants and then. released during relaxation, was at the origin of the observed P-EPOC. The effect of this 'hidden' promoter on the catalytic reaction rate was found to be highly non Faradaic.

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Type
research article
DOI
10.3311/pp.ch.2009-2.02
Web of Science ID

WOS:000274427700003

Author(s)
Foti, Gyoergy  
Date Issued

2009

Published in
Periodica Polytechnica-Chemical Engineering
Volume

53

Start page

41

End page

47

Subjects

Epoc

•

Permanent promotion

•

Pt/YSZ catalyst

•

Oxygen storage

•

Platinum

•

Oxidation

•

Oxygen

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GGEC  
Available on Infoscience
January 9, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/76471
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