Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Adsorbed and near surface structure of ionic liquids at a solid interface
 
research article

Adsorbed and near surface structure of ionic liquids at a solid interface

Segura, Juan Jose
•
Elbourne, Aaron
•
Wanless, Erica J.
Show more
2013
Physical Chemistry Chemical Physics

The structure of solid-ionic liquid (IL) interfaces has been characterised with unprecedented clarity by employing a range of atomic force microscopy (AFM) imaging techniques and tip pressures appropriate for the system under study. Soft contact and amplitude-modulation (AM) AFM imaging have been used to elucidate the lateral structure of ILs adsorbed onto mica, and in the near surface ion layers. Data is presented for ethylammonium nitrate (EAN) and 1-ethyl-3-methylimidazolium bis(trifluoro-methylsulfonyl)imide (EMIm TFSI). Whereas EAN is a protic IL that forms a nanostructured sponge phase in the bulk, EMIm TFSI is aprotic and has weak (or absent) bulk association structure. Comparison of results obtained for the two liquids elucidates how the strength of bulk liquid morphology effects lateral organisation at the surface, and any effect of IL class, i.e. protic versus aprotic. Imaging reveals EAN self assembles at the solid surface in a worm-like morphology, whereas EMIm cations adsorb in a more isolated fashion, but still in rows templated by the mica surface. To the authors' knowledge, the wormlike structures present at the EAN-mica interface are the smallest self-assembled aggregates ever imaged on a solid surface.

  • Details
  • Metrics
Type
research article
DOI
10.1039/c3cp44163f
Web of Science ID

WOS:000314651900037

Author(s)
Segura, Juan Jose
Elbourne, Aaron
Wanless, Erica J.
Warr, Gregory G.
Voitchovsky, Kislon  
Atkin, Rob
Date Issued

2013

Publisher

Royal Society of Chemistry

Published in
Physical Chemistry Chemical Physics
Volume

15

Issue

9

Start page

3320

End page

3328

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SUNMIL  
Available on Infoscience
March 28, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/90934
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés