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research article

Enhanced thermal stability and spin-lattice relaxation rate of N@C-60 inside carbon nanotubes

Toth, S.
•
Quintavalle, D.
•
Nafradi, B.  
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2008
Physical Review B

We studied the temperature stability of the endohedral fullerene molecule N@C-60 inside single-wall carbon nanotubes using electron-spin-resonance spectroscopy. We found that the nitrogen escapes at higher temperatures in the encapsulated material as compared to its pristine, crystalline form. The temperature dependent spin-lattice relaxation time T-1 of the encapsulated molecule is significantly shorter than that of the crystalline material, which is explained by the interaction of the nitrogen spin with the host nanotubes.

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Type
research article
DOI
10.1103/PhysRevB.77.214409
Web of Science ID

WOS:000257288900053

Author(s)
Toth, S.
•
Quintavalle, D.
•
Nafradi, B.  
•
Korecz, L.
•
Forro, L.  
•
Simon, F.
Date Issued

2008

Published in
Physical Review B
Volume

77

Article Number

214409

Subjects

C-60

•

Peapods

•

Phases

•

Epr

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPMC  
Available on Infoscience
November 30, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/61240
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