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  4. Degradation study of a reversible solid oxide cell (rSOC) short stack using distribution of relaxation times (DRT) analysis
 
research article

Degradation study of a reversible solid oxide cell (rSOC) short stack using distribution of relaxation times (DRT) analysis

Sampathkumar, Suhas Nuggehalli  
•
Aubin, Philippe  
•
Couturier, Karine
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February 28, 2022
International Journal Of Hydrogen Energy

Reversible solid oxide cells (rSOC) can convert excess electricity to valuable fuels in electrolysis cell mode (SOEC) and reverse the reaction in fuel cell mode (SOFC). In this work, a five - cell rSOC short stack, integrating fuel electrode (Ni-YSZ) supported solid oxide cells (Ni-YSZ parallel to YSZ vertical bar CGO parallel to LSC-CGO) with an active area of 100 cm(2), is tested for cyclic durability. The fuel electrode gases of H-2/N-2:50/50 and H-2/H2O:20/80 in SOFC and SOEC mode, respectively, are used during the 35 reversible operations. The voltage degradation of the rSOC is 1.64% kh(-1) and 0.65% kh(-1) in SOFC and SOEC mode, respectively, with fuel and steam utilisation of 52%. The post-cycle steady-state SOEC degradation of 0.74% kh(-1) suggests improved lifetime during rSOC conditions. The distribution of relaxation times (DRT) analysis suggests charge transfer through the fuel electrode is responsible for the observed degradation. (C) 2022 The Author(s). Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.

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Type
research article
DOI
10.1016/j.ijhydene.2022.01.104
Web of Science ID

WOS:000760317500004

Author(s)
Sampathkumar, Suhas Nuggehalli  
Aubin, Philippe  
Couturier, Karine
Sun, Xiufu
Sudireddy, Bhaskar Reddy
Diethelm, Stefan  
Perez-Fortes, Mar  
Van Herle, Jan  
Date Issued

2022-02-28

Publisher

PERGAMON-ELSEVIER SCIENCE LTD

Published in
International Journal Of Hydrogen Energy
Volume

47

Issue

18

Start page

10175

End page

10193

Subjects

Chemistry, Physical

•

Electrochemistry

•

Energy & Fuels

•

Chemistry

•

reversible solid oxide cell

•

rsoc

•

distribution of relaxation times

•

drt

•

rsoc degradation

•

temperature steam electrolysis

•

oxygen-electrode

•

fuel-cells

•

performance

•

sofc

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durability

•

model

•

generation

•

power

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-STI-JVH  
Available on Infoscience
March 28, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/186690
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