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research article

Molecular design of metal-free D–π-A substituted sensitizers for dye-sensitized solar cells

Alibabaei, L.
•
Kim, J.-H.
•
Wang, M.  
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2010
Energy & Environmental Science

Novel donor-p-acceptor (D--A) dyes, coded as SD-1, SD-2 and SD-5, were designed and synthesized for dye-sensitized solar cells. All these dyes comprised the same donor and acceptor units while the oligo thiophene units were introduced as linkers between the donor and acceptor units. The photophysical and electrochemical properties of the dyes were investigated by UV/vis spectrometry and cyclic voltammetry. The dyes were subsequently tested as sensitizers in dye-sensitized solar cells. Photovoltaic performance of the device with SD-2 dye showed maximum monochromatic incident photon-to-current efficiency (IPCE) of 82% and an over all conversion efficiency of 6.2% under full sunlight (AM 1.5G, 100 mW cm^2) irradiation.

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Type
research article
DOI
10.1039/c0ee00218f
Web of Science ID

WOS:000283602400014

Author(s)
Alibabaei, L.
Kim, J.-H.
Wang, M.  
Pootrakulchote, N.  
Teuscher, J.  
Di Censo, D.  
Humphry-Baker, R.  
Moser, J.-E.  
Yu, Y.-J.
Kay, K.-Y.
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Date Issued

2010

Published in
Energy & Environmental Science
Volume

3

Issue

11

Article Number

1757

Subjects

Interfacial Electron-Transfer

•

High-Efficiency

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Ruthenium Sensitizers

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Organic Sensitizers

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Highly Efficient

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Coumarin Dyes

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Tio2 Film

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Semiconductor

•

Photovoltaics

•

Performance

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-MO  
LPI  
Available on Infoscience
December 7, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/61961
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