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  4. Photodissociation of Alkyl Iodides in Helium Nanodroplets I: Kinetic Energy Transfer
 
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research article

Photodissociation of Alkyl Iodides in Helium Nanodroplets I: Kinetic Energy Transfer

Braun, Andreas
•
Drabbels, Marcel  
2007
The Journal of Chemical Physics

The photodissociation of (fluorinated) alkyl iodides in helium nanodroplets at a wavelength of 266 nm has been investigated by means of ion imaging techniques. It is found that a significant fraction of the created fragments escapes from the helium droplets. The speed and kinetic energy distributions of these fragments are found to be notably modified with respect to the corresponding gas phase distributions. The fragments, furthermore, show a speed dependent angular distribution. The loss of kinetic energy as well the reduction of the anisotropy parameter show a strong mass dependence. These observations point to a non-thermal escape process in which the kinetic energy and momentum transfer from the fragments to the solvent is governed by binary collisions with the individual helium atoms making up the droplet. Monte Carlo simulations based on hard sphere binary collisions substantiate this interpretation of the data.

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Type
research article
DOI
10.1063/1.2767261
Web of Science ID

WOS:000249667400018

Author(s)
Braun, Andreas
•
Drabbels, Marcel  
Date Issued

2007

Published in
The Journal of Chemical Physics
Volume

127

Article Number

114303

Subjects

helium droplets

•

alkyl iodide

•

photodissociation

•

dynamics

•

translation

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
April 26, 2007
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/6260
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