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research article
Pi-Allyl Palladium Methodology for Selective Deprotection of Allylamines. Practical Synthesis of Secondary Amines
The palladium-promoted deallylation of allylamines derived from primary and secondary amines is achieved with high to quantitative yield in the presence of 2-mercaptobenzoic acid as an allyl scavenger. This method was used for the sequential cleavage of diallylamines. A. synthetic application of this procedure is presented in the preparation of secondary amines from diallylamines.
Type
research article
Authors
Lemaire-Audoire, Sandrine
•
Savignac, Monique
•
Dupuis, Christophe
•
Genêt, Jean-Pierre
Publication date
1995
Published in
Volume
132
Issue
11
Start page
1157
End page
1166
Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
June 16, 2006
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