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  4. Cold-field-emission test of the fatigued state of Pb(ZrxTi1-x)O-3 films
 
research article

Cold-field-emission test of the fatigued state of Pb(ZrxTi1-x)O-3 films

Stolichnov, I.  
•
Tagantsev, A. K.  
•
Colla, E. L.
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1998
Applied Physics Letters

Fatigue phenomena occurring in Pb(ZrxTi1-x)O-3 ferroelectric thin-film capacitors (FECAP) with Pt electrodes are studied by means of conduction measurements in the cold-field-emission (tunneling) regime. We have determined that conduction in virgin FECAPs is controlled by tunneling at temperatures 100-140 K and electric fields (2.3-3.0 MV/cm). The Fowler-Nordheim equation successfully describes observed current-voltage relations for reasonable values of the semiconductor parameters of the system. Fatigue of the switching polarization induced by bipolar voltage cycling provokes a substantial increase in tunneling conduction, shifting the I-V curve to lower fields by some 0.5 MV/cm. The partial restoration of the switching polarization produced by heating of the sample up to 490 K results in a complete restoration of the initial current-voltage characteristic. It is shown that the fatigue-induced increase in conduction can be modeled by the charging of an interfacial layer of a thickness comparable with the tunneling length. This interpretation is consistent with a fatigue scenario related to the space-charge-assisted blocking of near-by-electrode centers of domain nucleation. (C) 1998 American Institute of Physics. [S0003-6951(98)03536-0].

  • Details
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Type
research article
DOI
10.1063/1.122374
Web of Science ID

WOS:000075786000018

Author(s)
Stolichnov, I.  
Tagantsev, A. K.  
Colla, E. L.
Setter, N.  
Date Issued

1998

Published in
Applied Physics Letters
Volume

73

Issue

10

Start page

1361

End page

1363

Subjects

ferroelectric thin-films

•

capacitors

Note

Stolichnov, I Swiss Fed Inst Technol, Ceram Lab, CH-1015 Lausanne, Switzerland Swiss Fed Inst Technol, Ceram Lab, CH-1015 Lausanne, Switzerland

117MU

Cited References Count:15

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233353
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