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  4. Polar phonons in some compressively stressed epitaxial and polycrystalline SrTiO3 thin films
 
research article

Polar phonons in some compressively stressed epitaxial and polycrystalline SrTiO3 thin films

Nuzhnyy, D
•
Petzelt, J.
•
Kamba, S.
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2009
Journal of Electroceramics

everal SrTiO3 (STO) thin films without electrodes processed by pulsed laser deposition, of thicknesses down to 40 nm, were studied using infrared transmission and reflection spectroscopy. The complex dielectric responses of polar phonon modes, particularly ferroelectric soft mode, in the films were determined quantitatively. The compressed epitaxial STO films on (100) La0.18Sr0.82Al0.59Ta0.41O3 substrates (strain 0.9%) show strongly stiffened phonon responses, whereas the soft mode in polycrystalline film on (0001) sapphire substrate shows a strong broadening due to grain boundaries and/or other inhomogeneities and defects. The stiffened soft mode is responsible for a much lower static permittivity in the plane of the compressed film than in the bulk samples.

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Type
research article
DOI
10.1007/s10832-008-9494-2
Web of Science ID

WOS:000263498800051

Author(s)
Nuzhnyy, D
Petzelt, J.
Kamba, S.
Yamada, T.  
Tyunina, M.
Tagantsev, A.K.
Levoska, J.
Setter, N.  
Date Issued

2009

Published in
Journal of Electroceramics
Volume

22

Issue

1

Start page

297

End page

301

Subjects

Soft mode

•

Thin film

•

Infrared spectroscopy

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
June 25, 2009
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/40871
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