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  4. Cross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complex
 
research article

Cross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complex

Vechorkin, Oleg  
•
Godinat, Aurélien  
•
Scopelliti, Rosario  
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2011
Angewandte Chemie International Edition

The nickel pincer complex 1 catalyzes the cross-coupling of the title compounds with remarkable substrate scope and functional group tolerance. A nickel/alkynyl species was isolated and shown to be catalytically competent. THF=tetrahydrofuran, O-TMEDA=bis[2-(N,N-dimethylaminoethyl)] ether.

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Type
research article
DOI
10.1002/anie.201105964
Web of Science ID

WOS:000298084900043

Author(s)
Vechorkin, Oleg  
Godinat, Aurélien  
Scopelliti, Rosario  
Hu, Xile  
Date Issued

2011

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Volume

50

Issue

49

Start page

11777

End page

11781

Subjects

alkylation

•

alkynes

•

cross-coupling

•

Grignard reaction

•

nickel

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSCI  
Available on Infoscience
September 24, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/71089
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