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  4. Thermal hysteresis in dithiadiazolyl and dithiazolyl radicals induced by supercooling of paramagnetic liquids close to room temperature: a study of F3CCNSSN and an interpretation of the behaviour of F3CCSNSCCF3
 
research article

Thermal hysteresis in dithiadiazolyl and dithiazolyl radicals induced by supercooling of paramagnetic liquids close to room temperature: a study of F3CCNSSN and an interpretation of the behaviour of F3CCSNSCCF3

Du, Hongbin
•
Haddon, Robert C.
•
Krossing, Ingo  
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2002
Chemical Communications (ChemComm)

The trifluoromethyl-substituted dithiadiazolyl and dithiazolyl radicals, F3CCNSSN (I) and F3CCSNSCCF3 (II) assoc. through p*-p* covalent and electrostatic Sd+...Nd- interactions in the solid state, but melt with a dramatic vol. increase to generate paramagnetic liqs.; these radicals exhibit thermal hysteresis, which arises through a meta-stable super-cooled liq. state, close to room temp. [on SciFinder (R)]

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Type
research article
DOI
10.1039/B202627A
Author(s)
Du, Hongbin
•
Haddon, Robert C.
•
Krossing, Ingo  
•
Passmore, Jack
•
Rawson, Jeremy M.
•
Schriver, Melbourne J.
Date Issued

2002

Publisher

Royal Society of Chemistry

Published in
Chemical Communications (ChemComm)
Issue

17

Start page

1836

End page

1837

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCIC  
Available on Infoscience
February 15, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/224065
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