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  4. Redox study of anode supported solid oxide fuel cell
 
conference poster not in proceedings

Redox study of anode supported solid oxide fuel cell

Faes, A.  
•
Hessler-Wyser, A.  
•
Brisse, A.
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2008
Fuel Cells Science and Technology 2008

The common technology for solid oxide fuel cells (SOFC) is based on a cermet anode of nickel with yttrium stabilized zirconia (YSZ), often used as the supporting structure. One of the main limitations of this anode technology is the redox tolerance. In this study, two techniques are used to quantify the anode expansion after one redox cycle at different temperatures. First, the increase of porosity is measured using scanning electron microscopy (SEM) image quantification. The second method considers the anode expansion above the electrolyte fracture limit by measuring the crack width in the electrolyte layer. An influence of redox cycling temperature on anode volume expansion was already observed by Ettler et al. but not fully understood. Here a model based on nickel oxidation mechanisms is proposed to explain the relation between redox temperature and volume expansion. The same methods are used to quantify anode expansion after consecutive redox cycles at constant temperature. In particular, small cracks caused at low oxidation temperature (600°C) were closed again after a subsequent reduction. The quantifying technique is then applied to cells tested in real stack conditions. The cell corners can undergo redox cycles depending on stack design and fuel utilization. The study of this location can give information on the number of cycles experienced by the anode support. Moreover, cracks in the electrolyte show infiltration of NiO that close the openings. Important infiltration can produce a short circuit between anode and cathode. The presence of strontium chromate on the infiltrated NiO was observed.

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Type
conference poster not in proceedings
Author(s)
Faes, A.  
Hessler-Wyser, A.  
Brisse, A.
Modena, S.
Van herle, J.  
Date Issued

2008

Subjects

RedOx

•

Anode-supported SOFC

•

Image analysis

•

Creep

•

Yttria-Stabilized Zirconia

•

High-Temperature Creep

•

Mechanical-Properties

•

Single-Crystals

•

Behavior

•

Reduction

•

Electrolytes

•

Membranes

•

Stacks

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
CIME  
LENI  
Event nameEvent placeEvent date
Fuel Cells Science and Technology 2008

Copenhagen

October 8-9, 2008

Available on Infoscience
December 22, 2008
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/32956
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