research article

Nitrogen oxide-catalyzed recombination of iodine atoms. Elementary steps of the complex mechanism

Van den Bergh, H.  
•
Troe, J.
1975
Chemical Physics Letters

The recombination of I atoms in the presence of NO was studied by laser flash photolysis in the inert gas He, at pressures between 1 and 200 atm and at temps. from 320-440 DegK. The elementary steps of the complex mechanism of the recombination were resolved. The fall-off curve of the interaction I + NO + He -> INO + He was measured as well as the equil. const. for I + NO .tautm. INO. The bond energy of INO is DH00 = 23 +- 3 kcal mole-1.

Type
research article
DOI
10.1016/0009-2614(75)85038-X
Author(s)
Van den Bergh, H.  
Troe, J.
Date Issued

1975

Publisher

Elsevier

Published in
Chemical Physics Letters
Volume

31

Issue

2

Start page

351

End page

354

Subjects

10102-43-9 Role: CAT (Catalyst use)

•

USES (Uses) (catalysis by

•

of iodine atom recombination)

•

14362-44-8 Role: RCT (Reactant)

•

RACT (Reactant or reagent) (recombination of

•

nitric oxide catalysis of)

•

nitric oxide catalysis iodine recombination

Note

Copyright 2003 ACS

CAPLUS

AN 1975:175753

CAN 82:175753

67-2

Catalysis and Reaction Kinetics

Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:

Journal

CHPLBC

written in English.

Recombination catalysts (nitric oxide, for iodine atoms); Recombination (of iodine atoms, mechanism of nitric oxide-catalyzed); Kinetics of recombination (of iodine atoms, with nitric oxide catalysis)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPAS  
Available on Infoscience
February 1, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/63603