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  4. AlN grown on Si(111) by ammonia-molecular beam epitaxy in the 900-1200 degrees C temperature range
 
research article

AlN grown on Si(111) by ammonia-molecular beam epitaxy in the 900-1200 degrees C temperature range

Tamariz, Sebastian  
•
Martin, Denis
•
Grandjean, Nicolas  
2017
Journal Of Crystal Growth

We present a comprehensive study of AlN growth on Si(111) substrate by gas source molecular beam epitaxy with ammonia as nitrogen precursor in the high temperature range. We first demonstrate that the observation of the silicon 7 x 7 surface reconstruction by reflection high energy electron diffraction can be misleading as this technique is not sensitive to low density surface defects like SiC crystallites. A careful in situ cleaning procedure with annealing cycles at 1100 degrees C allows getting rid of any surface defects, as shown by atomic force microscopy imaging. Then, we explore the effect of the growth temperature on the surface morphology and structural properties of 100 nm thick AlN epilayers. At 1200 degrees C, the growth proceeds with the step flow mode regime, which induces spiral-growth around screw-type dislocations and therefore surface roughening. On the other hand, a smooth surface morphology can be achieved by setting the temperature at 1100 degrees C, which corresponds to the growth mode transition from two-dimensional nucleation to step flow. A further decrease of the growth temperature to 900 degrees C to surface defects ascribed to polarity inversion domains. Similar defects are observed for growths performed at 1100 degrees C when the NH3 flow is reduced below 100 sccm. This points out the sensitivity of AlN to the surface stoichiometry. (C) 2017 The Authors. Published by Elsevier B. V. This is an open access article under the CC BY-NC-ND

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Type
research article
DOI
10.1016/j.jcrysgro.2017.08.006
Web of Science ID

WOS:000410917600010

Author(s)
Tamariz, Sebastian  
Martin, Denis
Grandjean, Nicolas  
Date Issued

2017

Publisher

Elsevier

Published in
Journal Of Crystal Growth
Volume

476

Start page

58

End page

63

Subjects

A3. Molecular beam epitaxy

•

B1. Nitrides

•

AlN on silicon

•

Ammonia molecular beam epitaxy

•

A1. Reflection high energy electron diffraction

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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Available on Infoscience
October 9, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/141155
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