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  4. Using Nanocavity Plasmons to Improve Solar Cell Efficiency
 
conference paper

Using Nanocavity Plasmons to Improve Solar Cell Efficiency

Soares, Bruno
•
Mahajan, Sumeet
•
Campbell, Andrew
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2009
Proceedings of the 11th International conference on transparent optical networks
ICTON: 11th International conference on transparent optical networks

Although in principle very promising, photovoltaic technology has so far failed to deliver robust high efficiency modules at affordable prices. Despite considerable research, high efficiency silicon based cells remain expensive, while the more recent organic photovoltaics are still struggling with low efficiencies and short lifetimes. Meanwhile, over the last few years, the study of localized plasmons has also received great attention due to the high field enhancements associated with confined fields, with a wide range of applications possible, from optical switches to substrates for surface enhanced Raman spectroscopy (SERS). Here we discuss how combining the structures normally used in photovoltaic devices with metallic cavities supporting localized plasmons can lead to considerable improvements in the performance of solar cells. In particular we show how by changing the shape and size of spherical voids on a metallic surface, one can tune the plasmon modes to obtain significant absorptions across the solar spectrum. By coating one such nanocavity surface with a sub 100 nm-layer of semiconductor, we can create a nanostructured solar cell, where the localised Mie modes efficiently couple light into the semiconductor layer. As the plasmons electric field enhancement is largest very close to the surface, significant absorption can be maintained even when the semiconductor thickness is reduced to below the typical exciton diffusion length. In addition minority carrier transport is improved. That means we can beat the usual balance between light absorption and exciton recombination loses, and so significantly increase the overall efficiency of the photovoltaic devices.

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Type
conference paper
DOI
10.1109/ICTON.2009.5185196
Author(s)
Soares, Bruno
Mahajan, Sumeet
Campbell, Andrew
Greenham, Neil
Guldin, Stefan  
Huettner, Sven
Steiner, Ullrich
Baumberg, Jeremy
Date Issued

2009

Publisher

IEE

Published in
Proceedings of the 11th International conference on transparent optical networks
ISBN of the book

978-1-4244-4825-8

Volume

1-2

Start page

1024

End page

1024

Subjects

plasmons

•

solar cells

•

nanostructured surfaces

Editorial or Peer reviewed

NON-REVIEWED

Written at

OTHER

EPFL units
IMX  
Event nameEvent placeEvent date
ICTON: 11th International conference on transparent optical networks

Azores

June 28 2009-July 2 2009

Available on Infoscience
January 31, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/88450
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