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research article

Domain annihilation due to temperature and thickness gradients in single-crystal BaTiO3

McGilly, L. J.
•
Burnett, T. L.
•
Schilling, A.
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2012
Physical Review B

The manner in which 90. ferroelectric-ferroelastic domains respond to changes in temperature has been mapped in BaTiO3 single crystals using atomic force microscopy. Domain periodicity remains unaltered until approximately 2 degrees C below the Curie temperature (T-C), whereupon domains coarsened dramatically. This behavior was successfully rationalized by considering the temperature dependence of the parameters associated with standard models of ferroelastic domain formation. However, while successful in describing the expected radical increase in equilibrium period with temperature, the model did not predict the unusual mechanism by which domain coarsening occurred; this was not continuous at a local level but instead involved discrete domain annihilation events. Subsequent insights from a combination of free energy analysis for the system and further experimental data from an analogous situation, in which domain period increases with increasing crystal thickness, suggested that domain annihilation is inevitablewhenever a component of the relevant gradient that affects domain period is orientated parallel to the domain walls. Consistent with this thesis, we note that, for the observations presented herein, the thermal gradient possessed a significant component parallel to the domain walls. We suggest that domain annihilation is a general feature of domain structures in gradient fields.

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Type
research article
DOI
10.1103/PhysRevB.85.054113
Web of Science ID

WOS:000300659000004

Author(s)
McGilly, L. J.
Burnett, T. L.
Schilling, A.
Cain, M. G.
Gregg, J. M.
Date Issued

2012

Published in
Physical Review B
Volume

85

Article Number

054113

Subjects

Ferroelectric Thin-Films

•

In-Situ Observation

•

Phase-Transitions

•

Barium-Titanate

•

Ferroelastic Films

•

Force Microscopy

•

Polarization

•

Surface

•

Energy

•

Flexoelectricity

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
IMX  
Available on Infoscience
March 22, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/78942
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